Indexes are not magic switches. They are data structures with tradeoffs, and the useful habit is learning how a query reaches the rows it needs.
Start with the query
Before adding an index, inspect the filter, sort, join, and selected columns. A composite index should match how the database narrows the search.
Read the execution plan
EXPLAIN helps show whether MySQL is scanning too much data, using the intended index, or paying for extra sorting.
Tradeoffs
Indexes speed up reads but add write cost and storage. The best index is tied to a real access pattern, not just a column that looks important.